Bio-chemo-mechanical processes in contaminated marine sediments

A detailed multi-scale investigation of the geotechnical, chemical and mineralogical properties was conducted on contaminated sediment samples collected within the Mar Piccolo, a marine basin in the south of Italy. The basin is located close to one of the most important industrial sites in Europe, which has also been declared ‘at high risk of environmental crisis’ and prioritised for remediation activities. A multidisciplinary investigation campaign showed that the samples collected close to the sea floor are characterised by high values of both heavy metals and organic pollutants and by the presence of significant amount of organic matter. Several samples in the top layer exhibited peculiar geotechnical properties, in terms of plasticity and activity indexes, compressibility and hydraulic permeability. While the prime suspect for such unconventional behaviour was chemo-mechanical coupling between the soil skeleton and contaminants, it turned out that the biogeochemical degradation of organic matter and the presence of microfossils and diatoms is likely to affect significantly the micro to macro behaviour of polluted marine sediments.